(Me3Si)2SiH anion

• Formula: C₆H₁₉Si₃^-
• Molecular weight: 175.4721
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C₆H₁₉Si₃^- +  = C₆H₂₀Si₃

By formula: C₆H₁₉Si₃^- + H⁺ = C₆H₂₀Si₃

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Protonation reactions

C₆H₁₉Si₃^- +  = C₆H₂₀Si₃

By formula: C₆H₁₉Si₃^- + H⁺ = C₆H₂₀Si₃

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Berger, et al., 1994
Brinkman, E.A.; Berger, S.; Brauman, J.I., alpha-Silyl-substituent stabilization of carbanions and silyl anions, J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042 . [all data]

Laarhoven, Mulder, et al., 1999
Laarhoven, L.J.J.; Mulder, P.; Wayner, D.D.M., Determination of bond dissociation enthalpies in solution by photoacoustic calorimetry, Acc. Chem. Res., 1999, 32, 4, 342-349, https://doi.org/10.1021/ar9703443 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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