C6F6..Au radical anion
- Formula: C6AuF6-
- Molecular weight: 383.0217
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
Au- + = C6AuF6-
By formula: Au- + C6F6 = C6AuF6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. ± 17. | kJ/mol | N/A | Ho and Dunbar, 1999 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
1.770 ± 0.070 | LPES | Sun, Tang, et al., 2013 | |
1.750 ± 0.030 | LPES | Nakajima, Taguwa, et al., 1993 | Vertical Detachment Energy: 1.990±0.048 eV |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ho and Dunbar, 1999
Ho, Y.P.; Dunbar, R.C.,
Reactions of Au+ and Au- with benzene and fluorine-substituted benzenes,
Int. J. Mass Spectrom., 1999, 183, 175-184, https://doi.org/10.1016/S1387-3806(98)14245-8
. [all data]
Sun, Tang, et al., 2013
Sun, Z.; Tang, Z.C.; Gao, Z.,
Half sandwich structures of MC6F6- (M = Ag and Au): An experimental and theoretical study,
J. Mol. Struct., 2013, 1032, 111-117, https://doi.org/10.1016/j.molstruc.2012.08.003
. [all data]
Nakajima, Taguwa, et al., 1993
Nakajima, A.; Taguwa, T.; Hoshino, K.; Sugioka, T.; Naganuma, T.; Ono, F.; Watanabe, K.; Nakao, K.,
Photoelectron Spectroscopy of (C6F6)n- and (Au-C6F6)- Clusters,
Chem. Phys. Lett., 1993, 214, 1, 22, https://doi.org/10.1016/0009-2614(93)85449-X
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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