Me3Al..H anion
- Formula: C3H10Al-
- Molecular weight: 73.0936
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | <-69.51 | kcal/mol | Ther | den Berg, Ingemann, et al., 1992 | Hydride affinity > (CF3)2CO. Computations indicate HOF(A-) ca. -46 kcal/mol, dHaff ca. 74 kcal/mol |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
den Berg, Ingemann, et al., 1992
den Berg, K.J. van; Ingemann, S.; Nibbering, N.M.M.,
Gas Phase Reactions of Negative Ions with Trimethylaluminum: Formation and Reactivity of the Me3AlH- Ion.,
Org. Mass Spectrom., 1992, 27, 4, 523, https://doi.org/10.1002/oms.1210270427
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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