(H2O)7..SO4 dianion

• Formula: H₁₄O₁₁S^-2
• Molecular weight: 222.171
• Information on this page:
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Ion clustering data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

H₁₂O₁₀S^-2 + 7 = H₁₄O₁₁S^-2

By formula: H₁₂O₁₀S^-2 + 7H₂O = H₁₄O₁₁S^-2

H₁₄O₁₁S^-2 + 8 = H₁₆O₁₂S^-2

By formula: H₁₄O₁₁S^-2 + 8H₂O = H₁₆O₁₂S^-2

References

Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Sergeeva, et al., 2009
Wang, X.B.; Sergeeva, A.P.; Yang, J.; Xing, X.P.; Boldyrev, A.I.; Wang, L.S., Photoelectron Spectroscopy of Cold Hydrated Sulfate Clusters, SO42-(H2O)(n) (n=4-7): Temperature-Dependent Isomer Populations, J. Phys. Chem. A, 2009, 113, 19, 5567-5576, https://doi.org/10.1021/jp900682g . [all data]

Wang, Nicholas, et al., 2000
Wang, X.B.; Nicholas, J.B.; Wang, L.S., Electronic instability of isolated SO42- and its solvation stabilization, J. Chem. Phys., 2000, 113, 24, 10837-10840, https://doi.org/10.1063/1.1333703 . [all data]

Blades and Kebarle, 2005
Blades, A.T.; Kebarle, P., Sequential hydration energies of the sulfate ion, from determinations of the equilibrium constants for the gas-phase reactions: SO4(H2O)(n)(2-) = SO4(H2O)(n-1)(2-)+H2O, J. Phys. Chem. A, 2005, 109, 37, 8293-8298, https://doi.org/10.1021/jp0540353 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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