1,2-diCO2Me-cyclopropanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7H9O4- + Hydrogen cation = C7H10O4

By formula: C7H9O4- + H+ = C7H10O4

Quantity Value Units Method Reference Comment
Δr375.1 ± 3.6kcal/molG+TSChou, Dahlke, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Δr366.9 ± 3.5kcal/molIMRBChou, Dahlke, et al., 1993gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C7H9O4- + Hydrogen cation = C7H10O4

By formula: C7H9O4- + H+ = C7H10O4

Quantity Value Units Method Reference Comment
Δr375.1 ± 3.6kcal/molG+TSChou, Dahlke, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Δr366.9 ± 3.5kcal/molIMRBChou, Dahlke, et al., 1993gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chou, Dahlke, et al., 1993
Chou, P.K.; Dahlke, G.D.; Kass, S.R., Unimolecular Rearrangements of Carbanions in the Gas Phase .2. Cyclopropyl Anions, J. Chem. Soc. Chem. Comm., 1993, 115, 1, 315, https://doi.org/10.1021/ja00054a045 . [all data]


Notes

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