(CO2)4..I anion


Gas phase thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1813.7kJ/molTherGomez, Taylor, et al., 2002EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.
Δfgas-1821.2kJ/molTherArnold, Bradforth, et al., 1995EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y)
Δfgas-1825.0kJ/molTherHiraoka, Mizuse, et al., 1987 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.6600 ± 0.0070LPESGomez, Taylor, et al., 2002EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.
3.695 ± 0.035LPESArnold, Bradforth, et al., 1995EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y)
3.790 ± 0.050LPESMarkovich, Giniger, et al., 1991Stated electron affinity is the Vertical Detachment Energy

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O., Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters, J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References