(CO2)2..I anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-241.4 ± 2.8kcal/molTherArnold, Bradforth, et al., 1995EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y)
Δfgas-242.5 ± 2.2kcal/molTherHiraoka, Mizuse, et al., 1987 
Δfgas-240.40kcal/molTherGomez, Taylor, et al., 2002EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.380 ± 0.035LPESArnold, Bradforth, et al., 1995EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y)
3.440 ± 0.050LPESMarkovich, Giniger, et al., 1991Stated electron affinity is the Vertical Detachment Energy
3.4850 ± 0.0070LPESGomez, Taylor, et al., 2002EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O., Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters, J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172 . [all data]


Notes

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