FSiH2NH anion
- Formula: FH3NSi-
- Molecular weight: 64.1150
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
H3FNSi- + = H4FNSi
By formula: H3FNSi- + H+ = H4FNSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1563. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1531. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
H3FNSi- + = H4FNSi
By formula: H3FNSi- + H+ = H4FNSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1563. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1531. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Krempp and Damrauer, 1995
Krempp, M.; Damrauer, R.,
The Gas-phase Chemistry of Silamide Ions,
Organomet., 1995, 14, 1, 170, https://doi.org/10.1021/om00001a027
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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