H3SiNH anion
- Formula: H4NSi-
- Molecular weight: 46.1245
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
H4NSi- + = H5NSi
By formula: H4NSi- + H+ = H5NSi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 375.5 ± 3.1 | kcal/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 368.0 ± 3.0 | kcal/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Krempp and Damrauer, 1995
Krempp, M.; Damrauer, R.,
The Gas-phase Chemistry of Silamide Ions,
Organomet., 1995, 14, 1, 170, https://doi.org/10.1021/om00001a027
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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