Me3Ge anion
- Formula: C3H9Ge-
- Molecular weight: 117.74
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C3H9Ge- + = C3H10Ge
By formula: C3H9Ge- + H+ = C3H10Ge
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1543. ± 8.8 | kJ/mol | D-EA | Brinkman, Salomon, et al., 1995 | gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2 |
| ΔrH° | 1514. ± 13. | kJ/mol | G+TS | Brinkman, Salomon, et al., 1995 | gas phase; Acidity between mF- and oF-aniline. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1512. ± 9.2 | kJ/mol | H-TS | Brinkman, Salomon, et al., 1995 | gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2 |
| ΔrG° | 1484. ± 13. | kJ/mol | IMRB | Brinkman, Salomon, et al., 1995 | gas phase; Acidity between mF- and oF-aniline. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I.,
Electron affinities and gas-phase acidities of organogermanium and organotin compounds,
J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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