CD3CH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H2D5O- + Hydrogen cation = C2H3D3O

By formula: C2H2D5O- + H+ = C2H3D3O

Quantity Value Units Method Reference Comment
Δr377.6 ± 2.3kcal/molG+TSDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio
Quantity Value Units Method Reference Comment
Δr371.0 ± 2.2kcal/molCIDCDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.7090 ± 0.0070LPESDang, Motell, et al., 1993 

Protonation reactions

C2H2D5O- + Hydrogen cation = C2H3D3O

By formula: C2H2D5O- + H+ = C2H3D3O

Quantity Value Units Method Reference Comment
Δr377.6 ± 2.3kcal/molG+TSDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio
Quantity Value Units Method Reference Comment
Δr371.0 ± 2.2kcal/molCIDCDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dang, Motell, et al., 1993
Dang, T.T.; Motell, E.L.; Travers, M.J.; Clifford, E.P.; Ellison, G.B.; Depuy, C.H.; Bierbaum, V.M., Experimental and Computational Studies of Deuterated Ethanols - Gas-Phase Acidities, Electron Affinities and Bond Dissociation Energies, Int. J. Mass Spectrom. Ion Proc., 1993, 123, 3, 171, https://doi.org/10.1016/0168-1176(93)87096-B . [all data]


Notes

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