L-Asparagine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H7N2O3- + Hydrogen cation = L-Asparagine

By formula: C4H7N2O3- + H+ = C4H8N2O3

Quantity Value Units Method Reference Comment
Δr331.0 ± 2.2kcal/molCIDCJones, Bernier, et al., 2007gas phase
Δr331.6 ± 3.1kcal/molG+TSO'Hair, Bowie, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr324.2 ± 2.3kcal/molH-TSJones, Bernier, et al., 2007gas phase
Δr324.8 ± 3.0kcal/molCIDCO'Hair, Bowie, et al., 1992gas phase

C4H7N2O3- + Water = C4H9N2O4-

By formula: C4H7N2O3- + H2O = C4H9N2O4-

Quantity Value Units Method Reference Comment
Δr12.30 ± 0.50kcal/molN/AWincel, 2008gas phase
Quantity Value Units Method Reference Comment
Δr4.4 ± 1.1kcal/molTDAsWincel, 2008gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jones, Bernier, et al., 2007
Jones, C.M.; Bernier, M.; Carson, E.; Colyer, K.E.; Metz, R.; Pawlow, A.; Wischow, E.D.; Webb, I.; Andriole, E.J.; Poutsma, J.C., Gas-phase Acities of the 20 Protein Amino Acids, Int. J. Mass Spectrom., 2007, 267, 1-3, 54-62, https://doi.org/10.1016/j.ijms.2007.02.018 . [all data]

O'Hair, Bowie, et al., 1992
O'Hair, R.J.; Bowie, J.H.; Gronert, S., Gas Phase Acidity of the alpha-Amino Acids, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 23, https://doi.org/10.1016/0168-1176(92)80083-D . [all data]

Wincel, 2008
Wincel, H., Hydration energies of deprotonated amino acids from gas phase equilibria measurements, J. Am. Soc. Mass Spectrom., 2008, 19, 8, 1091-1097, https://doi.org/10.1016/j.jasms.2008.05.014 . [all data]


Notes

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