1-vinylcyclopropanide anion
- Formula: C5H7-
- Molecular weight: 67.1096
- IUPAC Standard InChI: InChI=1S/C5H7/c1-2-5-3-4-5/h2H,1,3-4H2/q-1
- IUPAC Standard InChIKey: PAAQITHASMEPIA-UHFFFAOYSA-N
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
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| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 393.6 ± 3.1 | kcal/mol | G+TS | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 386.5 ± 3.0 | kcal/mol | IMRB | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
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=
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 393.6 ± 3.1 | kcal/mol | G+TS | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 386.5 ± 3.0 | kcal/mol | IMRB | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Guo and Kass, 1992
Guo, H.Z.; Kass, S.R.,
Vinylcyclopropyl Anion - Structure, Reactivity, Thermodynamic Properties, and an Unusual Rearrangement,
J. Am. Chem. Soc., 1992, 114, 4, 1244, https://doi.org/10.1021/ja00030a019
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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