1-vinylcyclopropanide anion
- Formula: C5H7-
- Molecular weight: 67.1096
- IUPAC Standard InChI: InChI=1S/C5H7/c1-2-5-3-4-5/h2H,1,3-4H2/q-1
- IUPAC Standard InChIKey: PAAQITHASMEPIA-UHFFFAOYSA-N
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
+
=
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 393.6 ± 3.1 | kcal/mol | G+TS | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 386.5 ± 3.0 | kcal/mol | IMRB | Guo and Kass, 1992 | gas phase; Between Me2NH, H2O |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Guo and Kass, 1992
Guo, H.Z.; Kass, S.R.,
Vinylcyclopropyl Anion - Structure, Reactivity, Thermodynamic Properties, and an Unusual Rearrangement,
J. Am. Chem. Soc., 1992, 114, 4, 1244, https://doi.org/10.1021/ja00030a019
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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