1-vinylcyclopropanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

1-vinylcyclopropanide anion + Hydrogen cation = Cyclopropane,ethenyl-

By formula: C5H7- + H+ = C5H8

Quantity Value Units Method Reference Comment
Δr393.6 ± 3.1kcal/molG+TSGuo and Kass, 1992gas phase; Between Me2NH, H2O
Quantity Value Units Method Reference Comment
Δr386.5 ± 3.0kcal/molIMRBGuo and Kass, 1992gas phase; Between Me2NH, H2O

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

1-vinylcyclopropanide anion + Hydrogen cation = Cyclopropane,ethenyl-

By formula: C5H7- + H+ = C5H8

Quantity Value Units Method Reference Comment
Δr393.6 ± 3.1kcal/molG+TSGuo and Kass, 1992gas phase; Between Me2NH, H2O
Quantity Value Units Method Reference Comment
Δr386.5 ± 3.0kcal/molIMRBGuo and Kass, 1992gas phase; Between Me2NH, H2O

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Kass, 1992
Guo, H.Z.; Kass, S.R., Vinylcyclopropyl Anion - Structure, Reactivity, Thermodynamic Properties, and an Unusual Rearrangement, J. Am. Chem. Soc., 1992, 114, 4, 1244, https://doi.org/10.1021/ja00030a019 . [all data]


Notes

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