VO3 radical anion
- Formula: O3V-
- Molecular weight: 98.9402
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -167.44 | kcal/mol | Ther | Bell, Zemski, et al., 2001 | |
| ΔfH°gas | -178.7 ± 2.8 | kcal/mol | TDEq | Rudnyi, Kaibicheva, et al., 1993 | value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 4.360 ± 0.050 | LPES | Wu and Wang, 1998 |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bell, Zemski, et al., 2001
Bell, R.C.; Zemski, K.A.; Justes, D.R.; Castleman, A.W.,
Formation, structure and bond dissociation thresholds of gas- phase vanadium oxide cluster ions,
J. Chem. Phys., 2001, 114, 2, 798-811, https://doi.org/10.1063/1.1329643
. [all data]
Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N.,
Negative Ions VO2(-), VO3(-), V2O5(-), V3O8(-), and V4O10(-) in the Vapors of Vanadium Oxides - Determining Enthalpies of Formation from Equ,
J. Chem. Thermodyn., 1993, 25, 8, 929, https://doi.org/10.1006/jcht.1993.1090
. [all data]
Wu and Wang, 1998
Wu, H.; Wang, L.-S.,
A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4),
J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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