VO3 radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-167.44kcal/molTherBell, Zemski, et al., 2001 
Δfgas-178.7 ± 2.8kcal/molTDEqRudnyi, Kaibicheva, et al., 1993value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
4.360 ± 0.050LPESWu and Wang, 1998 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bell, Zemski, et al., 2001
Bell, R.C.; Zemski, K.A.; Justes, D.R.; Castleman, A.W., Formation, structure and bond dissociation thresholds of gas- phase vanadium oxide cluster ions, J. Chem. Phys., 2001, 114, 2, 798-811, https://doi.org/10.1063/1.1329643 . [all data]

Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N., Negative Ions VO2(-), VO3(-), V2O5(-), V3O8(-), and V4O10(-) in the Vapors of Vanadium Oxides - Determining Enthalpies of Formation from Equ, J. Chem. Thermodyn., 1993, 25, 8, 929, https://doi.org/10.1006/jcht.1993.1090 . [all data]

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]


Notes

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