2,2,6,6-Me4-piperidinide anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.803 ± 0.092D-EAGrimm and Bartmess, 1992 

Protonation reactions

C9H18N- + Hydrogen cation = Piperidine, 2,2,6,6-tetramethyl-

By formula: C9H18N- + H+ = C9H19N

Quantity Value Units Method Reference Comment
Deltar1630.5 ± 3.0kJ/molG+TSGrimm and Bartmess, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar1599.5 ± 1.7kJ/molIMREGrimm and Bartmess, 1992gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimm and Bartmess, 1992
Grimm, D.T.; Bartmess, J.E., The Intrinsic (Gas Phase) Basicity of some Anions Commonly Used in Condensed-Phase Synthesis, J. Am. Chem. Soc., 1992, 114, 4, 1227, https://doi.org/10.1021/ja00030a016 . [all data]


Notes

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