MeAl(F)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3AlFO- + Hydrogen cation = CH4AlFO

By formula: CH3AlFO- + H+ = CH4AlFO

Quantity Value Units Method Reference Comment
Δr350.8 ± 4.1kcal/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc
Quantity Value Units Method Reference Comment
Δr344.0 ± 4.0kcal/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH3AlFO- + Hydrogen cation = CH4AlFO

By formula: CH3AlFO- + H+ = CH4AlFO

Quantity Value Units Method Reference Comment
Δr350.8 ± 4.1kcal/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc
Quantity Value Units Method Reference Comment
Δr344.0 ± 4.0kcal/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S., Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions, J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007 . [all data]


Notes

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