(MeO)3SiO anion
- Formula: C3H9O4Si-
- Molecular weight: 137.1872
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C3H9O4Si- + = C3H10O4Si
By formula: C3H9O4Si- + H+ = C3H10O4Si
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1484. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; Between MeSH, tBuSH |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1458. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; Between MeSH, tBuSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M.,
Effect of Substituents on the Gas-Phase Acidity of Silanols,
J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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