EtSi(Me)2O anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.17 ± 0.22D-EADamrauer, Simon, et al., 1991between pyrrole, CF3CH2OH

Protonation reactions

C4H11OSi- + Hydrogen cation = Silanol, ethyldimethyl-

By formula: C4H11OSi- + H+ = C4H12OSi

Quantity Value Units Method Reference Comment
Δr1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Δr1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]


Notes

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