Me2SiHO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H7OSi- + Hydrogen cation = Silanol, dimethyl-

By formula: C2H7OSi- + H+ = C2H8OSi

Quantity Value Units Method Reference Comment
Δr358.9 ± 4.1kcal/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Δr352.5 ± 4.0kcal/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]


Notes

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