HO(CH2)4O anion
- Formula: C4H9O2-
- Molecular weight: 89.1136
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C4H9O2- + =
By formula: C4H9O2- + H+ = C4H10O2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1490. ± 10. | kJ/mol | G+TS | Crowder and Bartmess, 1993 | gas phase; ΔGacid at 80°C |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1484. ± 8.4 | kJ/mol | IMRE | Crowder and Bartmess, 1993 | gas phase; ΔGacid at 80°C |
| ΔrG° | 1507.1 ± 1.3 | kJ/mol | CIDC | Houriet, Tabet, et al., 1984 | gas phase; value altered from reference due to change in acidity scale |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 2.67 ± 0.14 | D-EA | Crowder and Bartmess, 1993 | ΔGacid at 80°C |
Protonation reactions
C4H9O2- + =
By formula: C4H9O2- + H+ = C4H10O2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1490. ± 10. | kJ/mol | G+TS | Crowder and Bartmess, 1993 | gas phase; ΔGacid at 80°C |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1484. ± 8.4 | kJ/mol | IMRE | Crowder and Bartmess, 1993 | gas phase; ΔGacid at 80°C |
| ΔrG° | 1507.1 ± 1.3 | kJ/mol | CIDC | Houriet, Tabet, et al., 1984 | gas phase; value altered from reference due to change in acidity scale |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Crowder and Bartmess, 1993
Crowder, C.; Bartmess, J.,
The Gas Phase Acidities of Diols,
J. Am. Soc. Mass Spectrom., 1993, 4, 9, 723, https://doi.org/10.1016/1044-0305(93)80051-Y
. [all data]
Houriet, Tabet, et al., 1984
Houriet, R.; Tabet, J.-C.; Tchapla, A.,
Gas-phase Acidities of Aliphatic and Cyclic Diols,
Spectros. Int. J., (1984),, 1984, 3, 132.. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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