ONCH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH2NO2- + Hydrogen cation = CH3NO2

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Δr1538. ± 8.8kJ/molG+TSThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime
Quantity Value Units Method Reference Comment
Δr1510. ± 8.4kJ/molIMRBThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH2NO2- + Hydrogen cation = CH3NO2

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Δr1538. ± 8.8kJ/molG+TSThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime
Quantity Value Units Method Reference Comment
Δr1510. ± 8.4kJ/molIMRBThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Thomas, Bloor, et al., 1990
Thomas, D.A.; Bloor, J.E.; Bartmess, J.E., The Structures of the (M-H) Anions of the CH3NO2 Isomers Nitromethane and Methyl Nitrite, J. Am. Soc. Mass Spectrom., 1990, 1, 4, 295, https://doi.org/10.1016/1044-0305(90)85004-6 . [all data]


Notes

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