MeN=C(Me)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H6NO- + Hydrogen cation = Acetamide, N-methyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Δr361.8 ± 2.2kcal/molG+TSDecouzon, Exner, et al., 1990gas phase
Quantity Value Units Method Reference Comment
Δr354.5 ± 2.0kcal/molIMREDecouzon, Exner, et al., 1990gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.55 ± 0.16D-EADecouzon, Exner, et al., 1990 

Protonation reactions

C3H6NO- + Hydrogen cation = Acetamide, N-methyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Δr361.8 ± 2.2kcal/molG+TSDecouzon, Exner, et al., 1990gas phase
Quantity Value Units Method Reference Comment
Δr354.5 ± 2.0kcal/molIMREDecouzon, Exner, et al., 1990gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Decouzon, Exner, et al., 1990
Decouzon, M.; Exner, O.; Gal, J.-F.; Maria, P.-C., The Gas-Phase Acidity and the Acidic Site of Acetohydroxamic Acid: an FT-ICR Study, J. Org. Chem., 1990, 55, 13, 3980, https://doi.org/10.1021/jo00300a007 . [all data]


Notes

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