MeON=C(Me)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H6NO2- + Hydrogen cation = Acetamide, N-methoxy

By formula: C3H6NO2- + H+ = C3H7NO2

Quantity Value Units Method Reference Comment
Δr1469. ± 8.8kJ/molG+TSDecouzon, Exner, et al., 1990gas phase; Acid: O-methyl acetohydroxamic acid
Quantity Value Units Method Reference Comment
Δr1438. ± 8.4kJ/molIMREDecouzon, Exner, et al., 1990gas phase; Acid: O-methyl acetohydroxamic acid

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.28 ± 0.16D-EADecouzon, Exner, et al., 1990Acid: O-methyl acetohydroxamic acid

Protonation reactions

C3H6NO2- + Hydrogen cation = Acetamide, N-methoxy

By formula: C3H6NO2- + H+ = C3H7NO2

Quantity Value Units Method Reference Comment
Δr1469. ± 8.8kJ/molG+TSDecouzon, Exner, et al., 1990gas phase; Acid: O-methyl acetohydroxamic acid
Quantity Value Units Method Reference Comment
Δr1438. ± 8.4kJ/molIMREDecouzon, Exner, et al., 1990gas phase; Acid: O-methyl acetohydroxamic acid

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Decouzon, Exner, et al., 1990
Decouzon, M.; Exner, O.; Gal, J.-F.; Maria, P.-C., The Gas-Phase Acidity and the Acidic Site of Acetohydroxamic Acid: an FT-ICR Study, J. Org. Chem., 1990, 55, 13, 3980, https://doi.org/10.1021/jo00300a007 . [all data]


Notes

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