cPr-C(=O)-cyclopropanide anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H9O- + Hydrogen cation = Methanone, dicyclopropyl-

By formula: C7H9O- + H+ = C7H10O

Quantity Value Units Method Reference Comment
Δr1569. ± 17.kJ/molG+TSBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc
Quantity Value Units Method Reference Comment
Δr1540. ± 17.kJ/molIMRBBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C7H9O- + Hydrogen cation = Methanone, dicyclopropyl-

By formula: C7H9O- + H+ = C7H10O

Quantity Value Units Method Reference Comment
Δr1569. ± 17.kJ/molG+TSBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc
Quantity Value Units Method Reference Comment
Δr1540. ± 17.kJ/molIMRBBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brickhouse and Squires, 1988
Brickhouse, M.D.; Squires, R.R., Gas Phase Bronsted vs. Lewis Acid-Base Reactions of 6,6-Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions, J. Am. Chem. Soc., 1988, 110, 9, 2706, https://doi.org/10.1021/ja00217a002 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References