cPr-C(=O)-cyclopropanide anion
- Formula: C7H9O-
- Molecular weight: 109.1463
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C7H9O- + =
By formula: C7H9O- + H+ = C7H10O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1569. ± 17. | kJ/mol | G+TS | Brickhouse and Squires, 1988 | gas phase; Between EtOH, EtOAc |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1540. ± 17. | kJ/mol | IMRB | Brickhouse and Squires, 1988 | gas phase; Between EtOH, EtOAc |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brickhouse and Squires, 1988
Brickhouse, M.D.; Squires, R.R.,
Gas Phase Bronsted vs. Lewis Acid-Base Reactions of 6,6-Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions,
J. Am. Chem. Soc., 1988, 110, 9, 2706, https://doi.org/10.1021/ja00217a002
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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