CH2=CHC(Me)2CH2 anion
- Formula: C6H11-
- Molecular weight: 83.1521
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C6H11- + =
By formula: C6H11- + H+ = C6H12
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 409.0 ± 4.0 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 399.9 ± 4.1 | kcal/mol | H-TS | Graul and Squires, 1990 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.22 ± 0.19 | D-EA | Graul and Squires, 1990 |
Protonation reactions
C6H11- + =
By formula: C6H11- + H+ = C6H12
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 409.0 ± 4.0 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 399.9 ± 4.1 | kcal/mol | H-TS | Graul and Squires, 1990 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Graul and Squires, 1990
Graul, S.T.; Squires, R.R.,
Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions,
J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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