Co(PF3)4 anion
- Formula: CoF12P4-
- Molecular weight: 410.809630
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
CoF12P4- + = HCoF12P4
By formula: CoF12P4- + H+ = HCoF12P4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | <309.0 ± 4.0 | kcal/mol | IMRB | Miller, Kawamura, et al., 1990 | gas phase; More acidic than CF3SO3H |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
CoF12P4- + = HCoF12P4
By formula: CoF12P4- + H+ = HCoF12P4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | <309.0 ± 4.0 | kcal/mol | IMRB | Miller, Kawamura, et al., 1990 | gas phase; More acidic than CF3SO3H |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Miller, Kawamura, et al., 1990
Miller, A.E.S.; Kawamura, A.R.; Miller, T.M.,
Effects of Metal and Ligand Substitutions on Gas-Phase Acidities of Transition-Metal Hydrides,
J. Am. Chem. Soc., 1990, 112, 1, 457, https://doi.org/10.1021/ja00157a075
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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