Me2C=CHCO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H7O2- + Hydrogen cation = 2-Butenoic acid, 3-methyl-

By formula: C5H7O2- + H+ = C5H8O2

Quantity Value Units Method Reference Comment
Δr345.9 ± 2.2kcal/molG+TSCaldwell, Renneboog, et al., 1989gas phase
Quantity Value Units Method Reference Comment
Δr338.2 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase
Δr338.9 ± 2.0kcal/molIMRECaldwell, Renneboog, et al., 1989gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.50 ± 0.16D-EACaldwell, Renneboog, et al., 1989 

Protonation reactions

C5H7O2- + Hydrogen cation = 2-Butenoic acid, 3-methyl-

By formula: C5H7O2- + H+ = C5H8O2

Quantity Value Units Method Reference Comment
Δr345.9 ± 2.2kcal/molG+TSCaldwell, Renneboog, et al., 1989gas phase
Quantity Value Units Method Reference Comment
Δr338.2 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase
Δr338.9 ± 2.0kcal/molIMRECaldwell, Renneboog, et al., 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell, Renneboog, et al., 1989
Caldwell, G.; Renneboog, R.; Kebarle, P., Gas Phase Acidities of Aliphatic Carboxylic Acids, Based on Measurements of Proton Transfer Equilibria, Can. J. Chem., 1989, 67, 4, 661, https://doi.org/10.1139/v89-092 . [all data]

Graul, Schnute, et al., 1990
Graul, S.T.; Schnute, M.E.; Squires, R.R., Gas-Phase Acidities of Carboxylic Acids and Alcohols from Collision-Induced Dissociation of Dimer Cluster Ions, Int. J. Mass Spectrom. Ion Proc., 1990, 96, 2, 181, https://doi.org/10.1016/0168-1176(90)87028-F . [all data]


Notes

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