ZrF4..F anion
- Formula: F5Zr-
- Molecular weight: 186.217
- Information on this page:
- Other data available:
- Options:
Gas phase ion energetics data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
>7.799904 | LPES | Wang and Wang, 2000 | No detachment observed with 7.8 eV photons |
Ion clustering data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
F5Zr- + = F9Zr2-
By formula: F5Zr- + F4Zr = F9Zr2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.2 ± 1.0 | kcal/mol | TDAs | Skokan, Sorokin, et al., 1982 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang and Wang, 2000
Wang, X.B.; Wang, L.S.,
Experimental observation of a very high second electron affinity for ZrF6 from photodetachment of gaseous ZrF62- doubly charged anions,
J. Phys. Chem. A, 2000, 104, 19, 4429-4432, https://doi.org/10.1021/jp000362t
. [all data]
Skokan, Sorokin, et al., 1982
Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I.,
Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VI. Enthalpy of Formation of ZrF5-,
Int. J. Mass Spectrom. Ion Phys., 1982, 43, 4, 209, https://doi.org/10.1016/0020-7381(82)80017-X
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.