GeF4..F anion
- Formula: F5Ge-
- Molecular weight: 167.63
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -1856. ± 26. | kJ/mol | Latt | Mallouk, Rosenthal, et al., 1984 | Fluoride affinities from this method appear to be consistently about 10 kcal/mol too bound |
| ΔfH°gas | <-1843.5 | kJ/mol | Ther | Harland, Cradock, et al., 1972 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mallouk, Rosenthal, et al., 1984
Mallouk, T.E.; Rosenthal, G.L.; Muller, G.; Brusasco, R.; Bartlett, N.,
Fluoride ion affinities of GeF4 and BF4 from thermodynamic and structural data for (SF2)2GeF6, ClO2GeF5, and ClO2BF4,
Inorg. Chem., 1984, 23, 3167. [all data]
Harland, Cradock, et al., 1972
Harland, P.W.; Cradock, S.; Thynne, J.C.J.,
Positive- and negative-ion formation due to the electron bombardment of germanium tetrafluoride,
Int. J. Mass Spectrom. Ion Phys., 1972, 10, 169. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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