MnF2..F anion
- Formula: F3Mn-
- Molecular weight: 111.933803
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
By formula: F3Mn- + AlF4Li = AlF7LiMn-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 54.7 ± 2.0 | kcal/mol | TDAs | Sidorov and Gubarevich, 1982 | gas phase; At 1125K; value altered from reference due to conversion from electron convention to ion convention |
By formula: F3Mn- + F2Mn = F5Mn2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.1 ± 2.0 | kcal/mol | TDAs | Sidorov and Gubarevich, 1982 | gas phase; At 1125K; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.80 ± 0.30 | R-A | Boltalina, Borshchevskii, et al., 1992 | Critical review; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sidorov and Gubarevich, 1982
Sidorov, L.N.; Gubarevich, G.D.,
Dissociation of the Gaseous Complex Fluorides. Alkali Metal Trifluoromanganates and Tetrafluoromanganates,
Koord. Khim., 1982, 8, 12708c. [all data]
Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.,
Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase,
Russ. J. Phys. Chem., 1992, 66, 1223. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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