MnF2..F anion
- Formula: F3Mn-
- Molecular weight: 111.933803
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -1139. ± 19. | kJ/mol | Ther | Boltalina, Borshchevskii, et al., 1992 | Critical review; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.80 ± 0.30 | R-A | Boltalina, Borshchevskii, et al., 1992 | Critical review; value altered from reference due to conversion from electron convention to ion convention |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: F3Mn- + AlF4Li = AlF7LiMn-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 229. ± 8.4 | kJ/mol | TDAs | Sidorov and Gubarevich, 1982 | gas phase; At 1125K; value altered from reference due to conversion from electron convention to ion convention |
By formula: F3Mn- + F2Mn = F5Mn2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 205. ± 8.4 | kJ/mol | TDAs | Sidorov and Gubarevich, 1982 | gas phase; At 1125K; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.,
Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase,
Russ. J. Phys. Chem., 1992, 66, 1223. [all data]
Sidorov and Gubarevich, 1982
Sidorov, L.N.; Gubarevich, G.D.,
Dissociation of the Gaseous Complex Fluorides. Alkali Metal Trifluoromanganates and Tetrafluoromanganates,
Koord. Khim., 1982, 8, 12708c. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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