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Cl3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Deltar99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase
Deltar69.87kJ/molTherRobbiani and Franklin, 1979gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2
Deltar<182.4kJ/molPDisLee, Smith, et al., 1979gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S., Gas-phase thermochemistry of polyhalide anions, J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508 . [all data]

Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L., Formation of the trihalide ion Cl3- in the gas phase, J. Am. Chem. Soc., 1979, 101, 764. [all data]

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]


Notes

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