Cl3 anion
- Formula: Cl3-
- Molecular weight: 106.360
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
<4.640 ± 0.010 | LPES | Kaledin, Heaven, et al., 1999 | |
5.10 ± 0.20 | NBAE | Bowen, Liesegang, et al., 1983 | |
>4.30 ± 0.22 | R-A | Robbiani and Franklin, 1979 |
Ion clustering data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 99.2 ± 5.0 | kJ/mol | CIDT | Nizzi, Pommerening, et al., 1998 | gas phase |
ΔrH° | 69.87 | kJ/mol | Ther | Robbiani and Franklin, 1979, 2 | gas phase; ΔG≈+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2 |
ΔrH° | <182.4 | kJ/mol | PDis | Lee, Smith, et al., 1979 | gas phase |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kaledin, Heaven, et al., 1999
Kaledin, A.L.; Heaven, M.C.; Morokuma, K.; Neumark, D.M.,
Cl-3(-) electron photodetachment spectrum: measurement and assignment,
Chem. Phys. Lett., 1999, 306, 1-2, 48-52, https://doi.org/10.1016/S0009-2614(99)00419-4
. [all data]
Bowen, Liesegang, et al., 1983
Bowen, K.H.; Liesegang, G.W.; Sanders, R.A.; Herschbach, D.W.,
Electron Attachment to Molecular Clusters by Collisional Charge Transfer,
J. Phys. Chem., 1983, 87, 4, 557-565, https://doi.org/10.1021/j100227a009
. [all data]
Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L.,
Negative ion-molecule reaction in sulfuryl halides,
J. Am. Chem. Soc., 1979, 101, 3709. [all data]
Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S.,
Gas-phase thermochemistry of polyhalide anions,
J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508
. [all data]
Robbiani and Franklin, 1979, 2
Robbiani, R.; Franklin, J.L.,
Formation of the trihalide ion Cl3- in the gas phase,
J. Am. Chem. Soc., 1979, 101, 764. [all data]
Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A.,
Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-,
J. Chem. Phys., 1979, 70, 3237. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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