Cl3 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
<4.640 ± 0.010LPESKaledin, Heaven, et al., 1999 
5.10 ± 0.20NBAEBowen, Liesegang, et al., 1983 
>4.30 ± 0.22R-ARobbiani and Franklin, 1979 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Δr99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase
Δr69.87kJ/molTherRobbiani and Franklin, 1979, 2gas phase; ΔG≈+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2
Δr<182.4kJ/molPDisLee, Smith, et al., 1979gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kaledin, Heaven, et al., 1999
Kaledin, A.L.; Heaven, M.C.; Morokuma, K.; Neumark, D.M., Cl-3(-) electron photodetachment spectrum: measurement and assignment, Chem. Phys. Lett., 1999, 306, 1-2, 48-52, https://doi.org/10.1016/S0009-2614(99)00419-4 . [all data]

Bowen, Liesegang, et al., 1983
Bowen, K.H.; Liesegang, G.W.; Sanders, R.A.; Herschbach, D.W., Electron Attachment to Molecular Clusters by Collisional Charge Transfer, J. Phys. Chem., 1983, 87, 4, 557-565, https://doi.org/10.1021/j100227a009 . [all data]

Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L., Negative ion-molecule reaction in sulfuryl halides, J. Am. Chem. Soc., 1979, 101, 3709. [all data]

Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S., Gas-phase thermochemistry of polyhalide anions, J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508 . [all data]

Robbiani and Franklin, 1979, 2
Robbiani, R.; Franklin, J.L., Formation of the trihalide ion Cl3- in the gas phase, J. Am. Chem. Soc., 1979, 101, 764. [all data]

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]


Notes

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