AlF4 anion
- Formula: AlF4-
- Molecular weight: 102.9757000
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Clustering reactions
By formula: AlF4- + AlF3 = (AlF4- • AlF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 204. ± 4.2 | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 175. ± 8.4 | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
AlF4- + AlF4K = (AlF4- • AlF4K)
By formula: AlF4- + AlF4K = (AlF4- • AlF4K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 147. ± 6.3 | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 123. ± 10. | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
AlF4- + AlF4Na = (AlF4- • AlF4Na)
By formula: AlF4- + AlF4Na = (AlF4- • AlF4Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 166. ± 9.2 | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 141. ± 13. | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
By formula: AlF4- + BeF2 = (AlF4- • BeF2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 182. ± 10. | kJ/mol | TDAs | Nikitin, Sorokin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
AlF4- + BeF3K = (AlF4- • BeF3K)
By formula: AlF4- + BeF3K = (AlF4- • BeF3K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 192. ± 8.4 | kJ/mol | TDAs | Nikitin, Sorokin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
AlF4- + BeF3Na = (AlF4- • BeF3Na)
By formula: AlF4- + BeF3Na = (AlF4- • BeF3Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 192. ± 8.4 | kJ/mol | TDAs | Nikitin, Sorokin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
By formula: AlF4- + CoF3 = (AlF4- • CoF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 230. ± 50. | kJ/mol | Ther | Sidorov, Nikulin, et al., 1987 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
By formula: AlF4- + FK = (AlF4- • FK)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 120. ± 8.4 | kJ/mol | TDAs | Gusarov, Gorokhov, et al., 1979 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
By formula: AlF4- + F3Ga = (AlF4- • F3Ga)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 202. ± 18. | kJ/mol | TDEq | Zhuravleva, Nikitin, et al., 1985 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D.,
Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-,
Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]
Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N.,
Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems,
Russ. J. Phys. Chem., 1980, 54, page]. [all data]
Sidorov, Nikulin, et al., 1987
Sidorov, L.N.; Nikulin, V.V.; Chilingarov, N.S.; Korobov, M.V.,
The Enthalpy of Formation of the CoF4- Ion in the Gas Phase,
Russ. J. Phys. Chem., 1987, 61, 555. [all data]
Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V.,
Negative ions in the vapors of inorganic compounds,
Adv. Mass Spectrom., 1979, 8, 262. [all data]
Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N.,
Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF-..GaF3 Systems (M=Li, Na, K, Rb, Cs),
Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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