AlF4 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-463.4 ± 2.4kcal/molTherNikitin, Igolkina, et al., 1986Summary of literature data plus new work. Recommended average value at 0K.; value altered from reference due to conversion from electron convention to ion convention
Δfgas-500.0 ± 3.0kcal/molTDEqSrivastava, Uy, et al., 19742 AlF2 + AlF2- <=> 2AlF + AlF4-

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

AlF4- + Aluminum fluoride = (AlF4- • Aluminum fluoride)

By formula: AlF4- + AlF3 = (AlF4- • AlF3)

Quantity Value Units Method Reference Comment
Δr48.8 ± 1.0kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Δr41.8 ± 2.0kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + AlF4K = (AlF4- • AlF4K)

By formula: AlF4- + AlF4K = (AlF4- • AlF4K)

Quantity Value Units Method Reference Comment
Δr35.1 ± 1.5kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Δr29.5 ± 2.5kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + AlF4Na = (AlF4- • AlF4Na)

By formula: AlF4- + AlF4Na = (AlF4- • AlF4Na)

Quantity Value Units Method Reference Comment
Δr39.6 ± 2.2kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Δr33.6 ± 3.2kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF2 = (AlF4- • BeF2)

By formula: AlF4- + BeF2 = (AlF4- • BeF2)

Quantity Value Units Method Reference Comment
Δr43.5 ± 2.5kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF3K = (AlF4- • BeF3K)

By formula: AlF4- + BeF3K = (AlF4- • BeF3K)

Quantity Value Units Method Reference Comment
Δr45.8 ± 2.0kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF3Na = (AlF4- • BeF3Na)

By formula: AlF4- + BeF3Na = (AlF4- • BeF3Na)

Quantity Value Units Method Reference Comment
Δr45.9 ± 2.0kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + cobalt trifluoride = (AlF4- • cobalt trifluoride)

By formula: AlF4- + CoF3 = (AlF4- • CoF3)

Quantity Value Units Method Reference Comment
Δr55. ± 12.kcal/molTherSidorov, Nikulin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + Potassium fluoride = (AlF4- • Potassium fluoride)

By formula: AlF4- + FK = (AlF4- • FK)

Quantity Value Units Method Reference Comment
Δr28.6 ± 2.0kcal/molTDAsGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + F3Ga = (AlF4- • F3Ga)

By formula: AlF4- + F3Ga = (AlF4- • F3Ga)

Quantity Value Units Method Reference Comment
Δr48.3 ± 4.2kcal/molTDEqZhuravleva, Nikitin, et al., 1985gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]

Srivastava, Uy, et al., 1974
Srivastava, R.D.; Uy, O.M.; Farber, M., Experimental determination of heats of formation of negative ions and electron affinities of several boron and aluminum fluorides, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1033. [all data]

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]

Sidorov, Nikulin, et al., 1987
Sidorov, L.N.; Nikulin, V.V.; Chilingarov, N.S.; Korobov, M.V., The Enthalpy of Formation of the CoF4- Ion in the Gas Phase, Russ. J. Phys. Chem., 1987, 61, 555. [all data]

Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V., Negative ions in the vapors of inorganic compounds, Adv. Mass Spectrom., 1979, 8, 262. [all data]

Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF-..GaF3 Systems (M=Li, Na, K, Rb, Cs), Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6 . [all data]


Notes

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