Ru(Cp*)(PMe3)2(OH)
- Formula: C16H34OP2Ru
- Molecular weight: 405.46
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C16H34OP2Ru (solution) + (solution) = C28H43NP2Ru (solution) +
(solution)
By formula: C16H34OP2Ru (solution) + C12H11N (solution) = C28H43NP2Ru (solution) + H2O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1.2 ± 0.1 | kcal/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; In a series of reactions involving similar ruthenium complexes, the reaction enthalpy was identified with the reaction Gibbs energy, since the entropy values are expected to be small Bryndza, Fong, et al., 1987. For this reaction, however a van't Hoff plot could be used. Temperature range: 293-328 K |
| ΔrH° | 4.71 | kcal/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Benzene; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
C16H34OP2Ru (solution) + (solution) = C16H34P2Ru (solution) +
(solution)
By formula: C16H34OP2Ru (solution) + H2 (solution) = C16H34P2Ru (solution) + H2O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -5.90 ± 0.79 | kcal/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
C27H28OP2Pt (solution) + C28H43NP2Ru (solution) = C39H37NP2Pt (solution) + C16H34OP2Ru (solution)
By formula: C27H28OP2Pt (solution) + C28H43NP2Ru (solution) = C39H37NP2Pt (solution) + C16H34OP2Ru (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -3.61 | kcal/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; The reaction enthalpy can be identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
C16H34OP2Ru (solution) + (solution) = C17H33NP2Ru (solution) +
(solution)
By formula: C16H34OP2Ru (solution) + CHN (solution) = C17H33NP2Ru (solution) + H2O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <-9.39 | kcal/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
C16H34OP2Ru (solution) + (solution) = C17H36OP2Ru (solution) +
(solution)
By formula: C16H34OP2Ru (solution) + CH4O (solution) = C17H36OP2Ru (solution) + H2O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 0. | kcal/mol | EST | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bryndza, Fong, et al., 1987
Bryndza, H.E.; Fong, L.K.; Paciello, R.A.; Tam, W.; Bercaw, J.E.,
J. Am. Chem. Soc., 1987, 109, 1444. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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