Ru(Cp*)(PMe3)2(H)
- Formula: C16H34P2Ru
- Molecular weight: 389.46
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C16H34OP2Ru (solution) + (solution) = C16H34P2Ru (solution) +
(solution)
By formula: C16H34OP2Ru (solution) + H2 (solution) = C16H34P2Ru (solution) + H2O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -24.7 ± 3.3 | kJ/mol | EqS | Bryndza, Fong, et al., 1987 | solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987 |
C16H34P2Ru (solution) + (solution) = C16H33IP2Ru (solution) +
(solution)
By formula: C16H34P2Ru (solution) + CH3I (solution) = C16H33IP2Ru (solution) + CH4 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -188.3 ± 2.9 | kJ/mol | RSC | Luo, Li, et al., 1995 | solvent: Tetrahydrofuran |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bryndza, Fong, et al., 1987
Bryndza, H.E.; Fong, L.K.; Paciello, R.A.; Tam, W.; Bercaw, J.E.,
J. Am. Chem. Soc., 1987, 109, 1444. [all data]
Luo, Li, et al., 1995
Luo, L.; Li, C.; Cucullu, M.E.; Nolan, S.P.,
Organometallics, 1995, 14, 1333. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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