MnRe(CO)10
- Formula: C10MnO10Re
- Molecular weight: 521.246
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
(solution) +
(solution) = 2C10MnO10Re (solution)
By formula: C10Mn2O10 (solution) + C10O10Re2 (solution) = 2C10MnO10Re (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 121. ± 31. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; The reaction enthalpy was calculated from the enthalpies of the following reactions: Mn2(CO)10(solution) + I2(solution) = 2Mn(CO)5(I)(solution), -187.9 ± 8.4 kJ/mol, Re2(CO)10(solution) + I2(solution) = 2Re(CO)5(I)(solution), -157. ± 16. kJ/mol, and MnRe(CO)10(solution) + I2(solution) = Mn(CO)5(I)(solution) + Re(CO)5(I)(solution), -233. ± 13. kJ/mol |
| ΔrH° | 34.4 ± 1.3 | kJ/mol | EqS | Marcomini and Poë, 1984 | solvent: Decalin; Temperature range: 443-463 K |
C10MnO10Re (solution) + (solution) =
(solution) +
(solution)
By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -233. ± 13. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harel and Adamson, 1986
Harel, Y.; Adamson, A.W.,
J. Phys. Chem., 1986, 90, 6693. [all data]
Marcomini and Poë, 1984
Marcomini, A.; Poë, A.,
J. Chem. Soc., Dalton Trans., 1984, 95.. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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