Mn(CO)5(COPh)
- Formula: C12H5MnO6
- Molecular weight: 300.1025
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -202.6 ± 1.8 | kcal/mol | Review | Martinho Simões | The enthalpy formation relies on -140.8 ± 1.7 kcal/mol for the enthalpy of formation of Mn(CO)5(Ph)(g) |
| ΔfH°solid | -202.4 ± 1.2 | kcal/mol | Review | Martinho Simões | The enthalpy formation relies on -92.21 ± 0.41 kcal/mol for the enthalpy of formation of MnBr2(cr) Connor, Zafarani-Moattar, et al., 1982 |
| ΔfH°solid | -202.5 ± 1.1 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Connor, Zafarani-Moattar, et al., 1982 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C11H5MnO5 (solution) + (solution) = C12H5MnO6 (solution)
By formula: C11H5MnO5 (solution) + CO (solution) = C12H5MnO6 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -10.8 | kcal/mol | EqS | Calderazzo, 1977 | solvent: 2,2'-diethoxydiethyl ether |
C12H5MnO6 (cr) = C11H5MnO5 (g) + (g)
By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.4 ± 0.7 | kcal/mol | TD-HFC | Connor, Zafarani-Moattar, et al., 1982 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A.,
Organomet., 1982, 1, 1166. [all data]
Calderazzo, 1977
Calderazzo, F.,
Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]
Notes
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- Symbols used in this document:
ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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