Mn(CO)5(CH2F)

Formula: C₆H₂FMnO₅
Molecular weight: 228.0135
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Reaction thermochemistry data

Data compiled by: José A. Martinho Simões

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Individual Reactions

C₆H₂FMnO₅ (g) = C₅MnO₅ (g) + (g)

By formula: C₆H₂FMnO₅ (g) = C₅MnO₅ (g) + CH₂F (g)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	33.2 ± 3.6	kcal/mol	PIMS	Martinho Simões and Beauchamp, 1990	The reaction enthalpy was derived from the appearance energy of Mn(CO)5(+), 212.2 ± 1.1 kcal/mol, using Mn(CO)5(CH2F) as the neutral precursor, together with the adiabatic ionization energy of Mn(CO)5 radical, 179. ± 3.3 kcal/mol Martinho Simões and Beauchamp, 1990

References

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Martinho Simões and Beauchamp, 1990
Martinho Simões, J.A.; Beauchamp, J.L., Chem. Rev., 1990, 90, 629. [all data]

Notes

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Symbols used in this document:

Δ_rH° Enthalpy of reaction at standard conditions
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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