W(CO)4(CPh)(I)
- Formula: C11H5IO4W
- Molecular weight: 511.90
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C11H5IO4W (g) + (g) = C11H5BrO4W (g) +
(g)
By formula: C11H5IO4W (g) + Br (g) = C11H5BrO4W (g) + I (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -54. | kJ/mol | EqS | Fischer and Seitz, 1984 | The reaction enthalpy relies on a single measurement of the equilibrium constant in 1,1,2-trichloroethane (at 263 K) for the reaction W(CO)4(CPh)(I)(solution) + Br(-)(solution) = W(CO)4(CPh)(Br)(solution) + I(-)(solution), and on solvation and electron affinity data. It assumes that the reaction entropy is negligible Fischer and Seitz, 1984 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fischer and Seitz, 1984
Fischer, H.; Seitz, F.,
J. Organometal. Chem., 1984, 268, 247. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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