W(CO)4


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C5O5W (g) = C4O4W (g) + Carbon monoxide (g)

By formula: C5O5W (g) = C4O4W (g) + CO (g)

Quantity Value Units Method Reference Comment
Δr36.1 to 39.0kcal/molKinGRayner, Ishikawa, et al., 1991 
Δr40. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990The enthalpy of formation relies on -138.8 ± 3.1 kcal/mol for the enthalpy of formation of W(CO)5(g)

C4O4W (g) = C3O3W (g) + Carbon monoxide (g)

By formula: C4O4W (g) = C3O3W (g) + CO (g)

Quantity Value Units Method Reference Comment
Δr>33.0kcal/molKinGRayner, Ishikawa, et al., 1991 
Δr25. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rayner, Ishikawa, et al., 1991
Rayner, D.M.; Ishikawa, Y.; Brown, C.E.; Hackett, P.A., J. Chem. Phys., 1991, 94, 5471. [all data]

Venkataraman, Hou, et al., 1990
Venkataraman, B.; Hou, H.; Zhang, Z.; Chen, S.; Bandukwalla, G.; Vernon, M., J. Chem. Phys., 1990, 92, 5338. [all data]


Notes

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