W(Cp)2(OOCCF3)2
- Formula: C14H10F6O4W
- Molecular weight: 540.06
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -460.4 ± 1.9 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -15.1 ± 1.7 kcal/mol for the enthalpy of formation of W(Cp)2(Cl)2(cr) |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 22. ± 2.4 | kcal/mol | RSC | Calado, Dias, et al., 1981 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C14H10F6O4W (cr) + 2( • 4.40
) (solution) = C10H10Cl2W (cr) + 2
(l)
By formula: C14H10F6O4W (cr) + 2(HCl • 4.40H2O) (solution) = C10H10Cl2W (cr) + 2C2HF3O2 (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.62 ± 0.45 | kcal/mol | RSC | Calado, Dias, et al., 1981 | Please also see Calhorda, Carrondo, et al., 1986. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A.,
J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]
Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C.,
Organometallics, 1986, 5, 660. [all data]
Notes
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- Symbols used in this document:
ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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