[Mo(Cp*)(CO)3]2
- Formula: C26H30Mo2O6
- Molecular weight: 630.43
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
0.5C26H30Mo2O6 (solution) + (cr) = C13H15MoNaO3 (solution)
By formula: 0.5C26H30Mo2O6 (solution) + Na (cr) = C13H15MoNaO3 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -59.9 ± 1.4 | kcal/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp*)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp*)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -21.3 ± 0.60 kcal/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -38.50 ± 0.60 kcal/mol Kiss, Nolan, et al., 1994. |
C24H30Mo2O4 (solution) + 2 (solution) = C26H30Mo2O6 (solution)
By formula: C24H30Mo2O4 (solution) + 2CO (solution) = C26H30Mo2O6 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -32.89 ± 0.50 | kcal/mol | RSC | Nolan, López de la Vega, et al., 1986 | solvent: Toluene; The enthalpy of solution of [Mo(Cp*)(CO)2]2(cr) was measured as 3.5 ± 0.2 kcal/mol Nolan, López de la Vega, et al., 1986 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kiss, Nolan, et al., 1994
Kiss, G.; Nolan, S.P.; Hoff, C.D.,
Inorg. Chim. Acta, 1994, 227, 285. [all data]
Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
Inorg. Chem., 1986, 25, 4446. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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