Al(i-Bu)3


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-327.3kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.
Δfgas-231.5kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C24H54Al2 (l) = 2C12H27Al (l)

By formula: C24H54Al2 (l) = 2C12H27Al (l)

Quantity Value Units Method Reference Comment
Δr34.1 ± 0.5kJ/molEqSSmith, 1970 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1970
Smith, M.B., J. Organometal. Chem., 1970, 22, 273. [all data]


Notes

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