Al(i-Bu)3


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-327.3kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.
Δfgas-231.5kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-388.4 ± 7.7kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.
Δfliquid-293. ± 30.kJ/molReviewMartinho SimõesThe molar fraction of monomer in liquid tri-isobutylaluminum at 298 K is ca. 74% Smith, 1970.
Quantity Value Units Method Reference Comment
Δcliquid-9030.3 ± 7.5kJ/molCC-SBPawlenko, 1967Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.
Δcliquid-9126. ± 30.kJ/molCC-SBShaulov, Tubyanskaya, et al., 1964Please also see Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap61.1kJ/molCC-SBKnap, Leech, et al., 1957 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C24H54Al2 (l) = 2C12H27Al (l)

By formula: C24H54Al2 (l) = 2C12H27Al (l)

Quantity Value Units Method Reference Comment
Δr34.1 ± 0.5kJ/molEqSSmith, 1970 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1970
Smith, M.B., J. Organometal. Chem., 1970, 22, 273. [all data]

Pawlenko, 1967
Pawlenko, S., Chem. Ber., 1967, 100, 3591. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Shaulov, Tubyanskaya, et al., 1964
Shaulov, Y.K.; Tubyanskaya, V.S.; Evstegneeva, E.V.; Shmyreva, G.O., Russ. J. Phys. Chem., 1964, 38, 967. [all data]

Knap, Leech, et al., 1957
Knap, J.E.; Leech, R.E.; Reid, A.J.; Tamplin, W.S., Ind. Eng. Chem., 1957, 49, 874. [all data]


Notes

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